Select the currency you'll be exchanging from on the left, so in this case NEO, and the one you'll be exchanging for on the right, in this case WAVES.
Input the amount of NEO you want to sell for WAVES, paste the receiving address for your WAVES after the trade is done and click "TRADE".
Finally send the amount of NEO to the address that shows up on the screen by either copy-pasting the address shown on the page into your wallet or scanning the QR code on the right.
Sit back and wait
Make sure to note down the Trade ID shown on the page in case of issues with the trade.
Transactions can take a while to complete (often as long as an hour) so be patient.
If you encounter any issues contact Intercambio.app customer support with your Trade ID.